Zinc oxide hazards. agents and as gene carriers.
Zinc oxide hazards 030-013-00-7 EC No. 1. Zinc oxide ≥99 %, p. 9 µg/L Freshwater sediments 182. 5 /cell TRADE NAMES: Energizer, Hearwell, Overtime Approximate Weight: CHEMICAL SYSTEM: Silver Oxide-Zinc Designed for Recharge: No Energizer has prepared copyrighted Product Safety Datasheets to Chromium zinc oxide (Cr2ZnO4) | Cr2O4Zn | CID 72720432 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological Zinc oxide nanoparticles (ZnO NP) are one of the most commonly employed engineered nanomaterials worldwide due to their low cost and interesting properties, including chemical stability, catalytic ability, conductivity, photonic and optoelectronic, antifungal, antibacterial capacity as well as ability to block ultraviolet light. : 1313-96-8 1. Contact with magnesium and linseed oil Crude zinc oxide is a yellow-gray granular solid with no odor. Zinc oxide itself is non-toxic; it is hazardous, however, to inhale high concentrations of zinc oxide fumes, such as those Should Your Worry about Zinc in Your Denture Adhesive? Is Zinc in Denture Adhesive Safe. Contact with magnesium and linseed oil Zinc oxide ≥99 %, extra pure article number: 9348 Version: 3. Several studies reported the antibacterial, anticancer, antioxidant, and immunomodulatory effects of zinc oxide nanoparticles. Maize showed better growth when ZnO-NPs (50 mg L-1) were applied exogenously under Cd stress. In this review, we focus on zinc oxide nanoparticles destined for use in modern sunscreens, and discuss the potential for human exposure and the health hazard at each stage of their manufacture Hayashi Pure Chemical Ind. Federal Register / Vol. (Zinc oxide) Transport hazard class(es) Class: 9 Miscellaneous dangerous substances and articles Packing group:III Environmental hazard: Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. An official website of the United States government. * Contact can irritate the skin and eyes. A sputtering depth of 1. Zinc sulfide and zinc oxide are used to make white paints, ceramics, and other products. O. TOXICOLOGICAL INFORMATION Appearance Off-white Physical State Powder Solid Odor Odorless Odor Threshold No data available pH 5. Anthropogenic sources, such as metallurgical opera- Hazards not otherwise classified No specific dangers known, if the regulations/notes for storage and handling are considered. The intend of the current study was to explore the effects of zinc oxide nanoparticles (ZnO-NPs; 50 mg/L) on plant growth, photosynthetic activity, elemental status and antioxidant activity in Oryza sativa (rice) under Cd (0. The M-factor for acute and chronic aquatic effects is 10 and 1, respectively. Discover the world's research 25 Zinc iron oxide | Fe2H2O4Zn | CID 11831558 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. Relevant identified uses: For R&D use only. Additionally, the high isoelectric pH of 9. 1200 1. This generates fire and explosion hazard. 2 Additional information of impurities: Air No hazard identified PNECS relative to Zinc Oxide Environmental protection target PNECs Freshwater 17. C. 8 The dangers from these soaps are two-fold. 5 to 12 minutes experienced headaches, chills, and fever with cough and a decrease in vital capacity which Findings of our study highlighted that Trichoderma spp. The current study aims to green synthesis, characterization, and application of zinc-oxide nanoparticles to alleviate cadmium stress in maize (Zea mays L. SECTION 11. H410: Very toxic to aquatic life with long lasting effects. , 2019). Material Safety Data Sheet or SDS for Zinc oxide 108849 from Merck for download or viewing in the browser. Also, your health care professional may be able to tell you about ways to prevent or reduce some of these side effects. The ability of zinc oxide nanoparticles to release zinc is an important parameter from a risk assessment perspective (14). (NZnO) vs fine zinc oxide (FZnO) particulates, assess predictability of in vitro cell culture systems, and compare Additionally, to reduce the effect of oxide species formed on the surface of Cu particles upon exposure to air, Ar-ion sputtering was performed at 1 kV for 60 s for all samples, except for the calcined specimen. Product name : Niobium(V) oxide Product Number : 203920 Brand : Aldrich CAS-No. It is used in sunscreens, acting as a Zinc oxide sunscreen is a physical blocker that offers broad-spectrum protection against UV rays. : 1314-13-2 1. Precautionary statement(s) : Avoid release to the environment. All but two developed a mild fever between 6 and 12 hours after exposure and all but one reported more symptoms (particularly fatigue, muscle ache and cough) after zinc oxide exposure at 5 mg/m 3 than after Zinc Oxide Flinn Scientific, Inc. Incompatibilities: None have been identified. R. . 2 Special hazards arising from the substance or mixture Non-combustible. Interferences can be minimized by using, alternate angles of diffraction, computer-assisted methods of integration, or wide angle scans and subsequent ZINC OXIDE SCOPE. The main constituent is zinc oxide. When we talk about zinc oxide, it's crucial to recognize that its impact on health can vary greatly depending on the context in which it's encountered. to GHS Section Hazard class Cat-egory Hazard class and category Hazard Zinc oxide (ZnO) is one of the high-volume production nanoparticles (NPs) currently used in a wide range of consumer and industrial goods. 1007/s43630-021-00101-2 Cite NAME CAS RN % HAZARDOUS Zinc oxide 1314-13-2 >90 Yes SYNONYMS: Flowers of Zinc; Zinc Monoxide; Zinc White; Global Supa Zinc. , USP Article number 5297 Index No (GB CLP) 030-013-00-7 EC number 215-222-5 SECTION 2: Hazards identification 2. Product name: Zinc sulfide; CBnumber: CB0733609; CAS: 1314-98-3; EINECS Number: 215-251-3; Synonyms: zinc sulfide,zinc sulphide; Relevant identified uses of the substance or mixture and uses advised against. Cadmium (Cd) can induce programmed cell death (PCD) and zinc oxide nanoparticles (ZnO NPs) effectively alleviate Cd stress. 3. That suggests zinc oxide particles are leading to degradants whose introduction to aquatic ecosystems is environmentally hazardous. 1 Safety Data Sheet according to WHS and ADG requirements zinc oxide Zinc oxide 10 mg/m3 15 mg/m3 2,500 mg/m3 Ingredient Original IDLH Revised IDLH zinc oxide 500 mg/m3 Not Available Exposure controls Appropriate engineering Zinc-oxide nanoparticles ameliorated the phytotoxic hazards of cadmium toxicity in maize plants by regulating primary metabolites and antioxidants activity. Product identifier. 1314-13-2 EU Index No. Does not contain an endocrine disruptor For full text of R-phrases and Hazard- and EU Hazard-statements: see Section 16. Composition / Information on Ingredients According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910. to GHS Section Hazard class Cat-egory Hazard class and category Hazard Apply zinc oxide cream directly to the affected area, including skin suffering from a diaper rash, redness, chafing, burns, poison ivy or skin irritation. Classification of the substance or mixture Hazardous polymerization or runaway reactions will not occur. Gels These supplements may contain different forms of zinc like zinc gluconate, zinc sulfate, and zinc acetate. Aluminum Zinc Oxide (powder and pieces) According to Appendix D, OSHA Hazard Communication Standard 29 CFR §1910. 3 Effective date : 01. Zinc oxide often leaves an annoying white cast on the skin that may be a dealbreaker for some. 1200 Carbonic acid, ammonium zinc salt (2:2:1) CAS Number: 40861-29-8 Here, using tomato as the material, we analyzed the effect of foliar spraying with zinc oxide nanoparticles (ZnO NPs) on Cd accumulation and tolerance in tomato seedlings. Toxicity Although zinc oxide nanoparticles (ZnO NPs) have been widely used, their potential hazards on mammalian and human remain largely unknown. Zinc oxide and chlorinated rubber reacts violently at 215 deg C. They use the potassium hydroxide solution, also known as caustic potash, that is an inorganic compound ( Schultz et al. have greater ability to grow under varying Zinc and Lead concentration and shows greater tolerance limit of 0. The EWG VERIFIED ® mark means a product meets EWG’s strictest criteria for transparency and health. 10. Product Identifiers: Zinc Oxide Ointment, Dynarex Reorder # 1190, 1191, 1192 Other means of identification: Zinc Oxide (Ointment) Recommended use of the chemical Directions Unusual Fire and Explosion Hazards: Zinc oxide fume. Identification of the substance/mixture and of the company/undertaking Hazard classification & labelling Hazard classification and labelling The ‘Hazard classification and labelling’ section shows the hazards of a substance based on the standardised system of statements and pictograms established under the CLP (Classification Labelling and Packaging) Regulation. Workers should receive training on the hazards of zinc oxide fumes, proper welding techniques, use of ventilation systems, and the importance of wearing PPE. s. Moreover, a recent National Academy of Sciences report predicts that future hazard testing will be conducted primarily using cell culture assays. Photochemical & Photobiological Sciences , 2021; 20 (10): 1273 DOI: 10. Lozenges. It provides the first evidence that zinc-oxide nanoparticles 25 ~ 50 mg L⁻¹ can be a candidate agricultural strategy for mitigating cadmium stress in cadmium-polluted soils for safe agriculture Possibility of hazardous reactions: Under normal conditions of storage and use, hazardous reactions will not occur. Zinc oxide nanoparticles in modern sunscreens: An analysis of potential exposure and hazard MEGAN J. They can form agglomerates or pustules that interfere with the appearance of a painting by becoming mobile and breaking through to the surface. Identification Product identifier Product name Aluminum Zinc Oxide (powder and pieces) Internal identification Replaces M-2201-335, M-2201-336 Recommended use of the chemical and restrictions on use Application Exterior Toxicological Hazards of Zinc Oxide Nanoparticles In recent years, a number of studies have shown the possibility of using zinc oxide nanoparticles as therapeutic agents and as gene carriers. The use of metal oxide nanoparticles in food processing and agriculture sectors have tremendously increased in recent years (Dasgupta et al. EYE One of the most prevalent health hazards associated with zinc oxide fumes is metal fume fever. No data. The Skin Deep ingredient hazard score, from 1 to 10, reflects known and suspected hazards linked to the ingredients. A 39-year-old man showed nausea, vomiting, and abdominal pain six hours after ingesting 150 g of a 10% zinc oxide lotion, but without signs of systemic toxicity. Therefore zinc oxide vapor can absolutely be created by grinding galvanized steel without "melting" the base metal in a welding operation or otherwise. Human data: Workers exposed to zinc concentrations between 320 to 580 mg/m 3 for 1-3 hours have experienced nausea on the job, and chills, shortness of breath, and severe NIOSH: Pocket Guide to Chemical Hazards - Zinc oxide Literature References NOAA: CAMEO Chemicals - Zinc Peroxide. 101) to assist in preparing a risk assessment for loading, transporting and storing hazardous materials. a. Overall, the foliar efficacy of ZnO-NPs enhanced the tolerance Possibility of hazardous reactions Zinc oxide and magnesium metal filings or powder can react violently when heated. Dispose of contents/ container to an approved waste disposal plant. 2% in roots and In addition, Zn contamination in the soil may pose risks and hazards to humans and the ecosystem through direct ingestion or contact with contaminated soil, the food chain Zinc oxide is harmless, and used to degrade the contaminated material of the environment . 1200) Haz Com 2012 Product: Zinc Oxide (REF 310 -16200, 310 -16250, 310 -16300) Revision Date: 11/09 /2015 Page 1 of 12 Zinc Oxide (REF 310-16200, 310-16250, 310-16300) SDS SECTION 1 - IDENTIFICATION Product Identifier Product Name: Zinc Oxide, USP Zinc oxide nanoparticles were reported to have therapeutic benefits. 5 of ZnO-NPs allows for protein adsorption by electrostatic contact. Common Name: ZINC OXIDE CAS Number: 1314-13-2 DOT Number: UN 3077 DOT Hazard Class: 9 (Miscellaneous Hazardous Material) ----- HAZARD SUMMARY * Zinc Oxide can affect Important additional information about respirator selection. It is based on silver-oxide/-zinc chemistry and can provide very high energy to weight performance. Zinc may contain trace amounts of arsenic, when forming hydrogen, may also form toxic gas arsine (see ICSC0001 and ICSC0222). Zinc oxide is a mild astringent used in personal care and cosmetic products. Here is how you know Zinc oxide (ZnO) nanoparticles (NPs) are widely utilized in biosensor applications because to their optical characteristics, polymorphic nature, ease of manufacturing, and high electron mobility. , 2016). To this end, the rice plants are treated by Cd stress at 15 days after sowing (DAS), and the treatment was Crude zinc oxide is a yellow-gray granular solid with no odor. Zinc oxide is used in glass, frits, enamels and ferrites. 1. to GHS Section Hazard class Cat-egory Hazard class and category Hazard Hazard score. Title: Microsoft Word - ZCX006 Foliar spraying of zinc oxide nanoparticles improves water transport cinogen and is ranked seventh out of the 20 most hazardous metals. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 Aspiration hazard : Not classified ZINC OXIDE AR (1314-13-2) Viscosity, kinematic Not applicable SECTION 12: Ecological information 12. , 2000 ). Zinc oxide Revision date: 8/31/2023 SDS code: F5-14 Version: 06 2/7 Specific target organ toxicity (repeated exposure) classification not possible Aspiration hazard classification not possible Environmental hazards Hazardous to the aquatic environment, short-term (acute) Category 1 Hazardous to the aquatic Zinc oxide-induced changes to sunscreen ingredient efficacy and toxicity under UV irradiation. An 8-hr threshold limit value (TLV) of 5 mg/m3 has been established to prevent adverse health effects because of exposure t In conclusion, zinc oxide is classified for hazards to the aquatic environment under CLP as H400 ("Acute 1"), H410 ("Chronic 1"). Short of causing metal fume fever, zinc chloride released while cutting galvanized steel can produce a host of other side effects. Contact with little immediate hazard to the health of emergency response personnel or to the environment in an emergency situation. 42 nm was used for SiO 2. Eur. First aid is not generally required. Identification of the substance Zinc oxide ≥99 %, Ph. Zinc oxide is used as a flux; it often enhances color response, especially in copper and cobalt glazes. No Special precautions for users. Zinc supplements come in many forms including: Pills. It is a white powder which is insoluble in water. 0 m2/g surface area and Human data: Workers exposed to zinc concentrations between 320 to 580 mg/m 3 for 1-3 hours have experienced nausea on the job, and chills, shortness of breath, and severe chest pains 2 to 12 hours later [Hammond 1944]. Pigment White 4: CAS #: 1314-13-2: UN #: 3077 EC Number: 215-222-5 ACUTE HAZARDS PREVENTION Physical dangers. 4 Conditions to avoid No data available 10. 3 Precautions for fire-fighters: Protective equipment: Fire fighters must be fully trained and wear full protective clothing including an approved, self Zinc Oxide - Eugenol Temporary Cement Paste. ZINC OXIDE: ICSC: 0208 (April 2017) Zinc white Zinc monoxide C. An official website of the United States government Hazardous Chemical Information System (HCIS), Safe Work Australia. Posted: 06. Section 4 - FIRST AID MEASURES SWALLOWED Immediately give a glass of water. ) plants. In this they are not The development of accurate in vitro screening assays to assess lung hazard potential of nanomaterials is a highly desirable goal. Zinc borate oxide chemical information summary. [1] [unreliable medical source?] Excessive absorption of zinc can suppress copper and iron absorption. The development of accurate in vitro screening assays to assess lung hazard potential of nanomaterials is a highly desirable goal. FDA also has also approved the use of zinc oxide for use in over-the-counter skin Page 1 of 4 Silver Oxide Batteries January 2016 ©2016 Energizer PRODUCT SAFETY DATA SHEET PRODUCT NAME: Energizer Battery Type No. 0 micron aerodynamic diameter) produces a well-characterized response known as metal fume fever. Most zinc ore found naturally in the environment is in the form of zinc sulfide. Hazard Pictogram(s) Hazard Statement(s) H410: Very toxic to aquatic life with long lasting effects. 2, G CAS-No. Immediate steps should be taken to limit its spread to the environment. and most global jurisdictions. Although it may seem like a mild sickness, it should not be taken lightly as prolonged exposure can lead to severe health complications. Accidental Release Measures When Material is Released or Spilled: Assure slippery conditions are Zinc has good corrosion resistance and is used to plate or galvanize steel to prevent corrosion. Zinc supplements are available over the counter (OTC) at retail pharmacies, wellness stores, grocery stores, and from online retailers. By Chris Brown. Additionally, zinc oxide nanoparticles were used in sunscreens. It is used as a textile Owing to the industrial revolution, the mass production of zinc oxide (ZnO) has been led to contaminated environments, and therefore, the toxicological effects of ZnO become more concerning under climate change scenarios. Zinc toxicity is a medical condition involving an overdose on, or toxic overexposure to, zinc. Hazard Statement Code(s) Hazard Statement Code(s) Supplementary Hazard Statement Code(s) Pictograms, Signal Word Code(s) Aquatic Acute 1 H400 GHS09 Wng : Aquatic Chronic 1 Zinc oxide: 1314-13-2: Notified classification and labelling according to CLP criteria Classification Labelling Specific Concentration limits, M-Factors ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N. Welding galvanized steel presents a number of health dangers, primarily stemming from inhaling the harmful zinc oxide fumes produced during the procedure. It improves wound healing, helps lower acne breakouts and supports moisture retention in skin. This SDS is not valid where zinc oxide is listed as transportation regulated which includes, but not limited to, European Union member states, P. , 2021, Reddy et al. It was common to see the signature white streaks of zinc oxide along fellow surfers' noses and upper cheeks. Very (ZINC OXIDE) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N. OSMOND, & MAXINE J. , and Japan. 0 Stability and reactivity 10. Other means of identification:Zinc Oxide - Eugenol Temporary Cement Toxicological Hazards of Zinc Oxide Nanoparticles. Tunnel code (E). Zinc oxide (<=33 %) 10. Safety Data Sheet for Zinc oxide 108849. Conditions to avoid: No specific data. These toxic Other side effects of zinc oxide topical. Food and Drug Administration (FDA) has conducted extensive reviews of the safety of zinc oxide for use as a color additive in drugs and cosmetics and as a sunscreen and skin protectant active ingredient and has stated that zinc oxide may be safely used in cosmetics. Share: 5. 8 mM) stress. (Zinc Oxide) Transport hazard Classes: 9 Packing group: III Environmental hazards: Yes. In recent years, a number of studies have shown the possibility of using zinc oxide nanoparticles as therapeutic. 13 Evaporation rate Not applicable 10. This SDS is compliant with GHS and regulations for United States, Canada, Mexico, Brazil, Columbia, Thailand, Singapore, etc. However, the mechanisms of ZnO NPs-mediated Cd detoxification in alfalfa (Medicago sativa L. These side effects may go away during treatment as your body adjusts to the medicine. 2 Hazard Classes and Categories. , 2017, Rossi et al. Not for medicinal, household or other use. Catalog Number 108849 Product Name Zinc oxide. Hazards Identification Pictograms of hazard symbol (referring to zinc oxide) Hazard statement(s): Very toxic to aquatic life with long lasting effects . Nasal sprays. Identification are classified as hazardous to health and hence require reporting in this section. According to the results of its assessment, this substance is not a PBT or a vPvB. It is insoluble in water. doc Page 4. " Zinc oxide dust is generally considered a nuisance dust; adverse effects are unlikely when exposures are Physical dangers. Violent reactions possible with hydrogen peroxide. Hazard Statements : H400 - Very toxic to aquatic life. 2 en Replaces version of: 2024-09-18 Version: (3) date of compilation: 2020-10-30 SECTION 2: Hazards identification 2. Nanocrystalline zinc oxide materials were prepared by sol–gel method and were characterized by X-ray diffraction, scanning electron microscopy, thermogravimetry, nitrogen adsorption and Boron zinc oxide (B6Zn2O11), hydrate chemical information summary. For that reason, SZB are used in torpedoes, aircrafts and missiles of various types. Some of the benefits of zinc oxide sunscreen include instant efficacy and potentially fewer side effects. The use of zinc in standard glazes is limited by its price, its hostility to the development of certain colors and its tendency to make glazes more leachable in acids (although zinc itself is not considered a hazardous substance). Let’s explore some of its common uses: Sunscreen and Skincare Products: Zinc oxide is a key ingredient in sunscreen Zinc oxide fume is formed when zinc metal is heated to or near the boiling point or is burned. IDENTIFICATION Zinc Borate is a white powder. The hazard levels for each human or Zinc oxide is an inorganic compound with the formula Zn O. However, some studies have noted little correlation between in vitro and in vivo results. Zinc peroxide White, odorless solid. * Breathing Zinc Borate can irritate the nose and throat causing coughing and wheezing. 0%, ZINC OXIDE(SUNSCREEN GRADE) EU GHS Hazard Labeling Codes: GHS Hazard Codes. Your body absorbs each of these forms 2. Brazing, welding base metal, plating, or even soldering can also lead to metal poisoning as a result of exposure to copper, zinc, lead, or cadmium. P273: Avoid A few sources claim that finely divided zinc oxide dust can cause "metal fume fever. Product name ZINC OXIDE Synonyms, Trade Names Zinc Oxide No. Conforms with OSHA Hazard Comm unication Standard (CFR 29 1910. The primary hazard is the threat posed to the environment. Chemical dangers Reacts violently with aluminium powder, magnesium powder and chlorinated rubber (on heating). 77, No. 1 minute to read. When zinc is heated to temperatures above 500°C (932° F) in the flame during oxygen cutting or in the arc during welding, zinc oxide particles are released into the air as zinc oxide fume. Some side effects of zinc oxide topical may occur that usually do not need medical attention. Composition / Information on Ingredients Skin: No known significant effects or critical hazards. Substance information for UN 1713 - Zinc cyanide based on the Hazardous Materials Table (Title 49 CFR 172. 2. ACGIH: Documentation of the threshold limit Spillage and fire water can cause pollution of watercourses. One study asked 12 healthy volunteers to inhale zinc oxide fumes through a mask for two hours at 0, 2. ZINC OXIDE MATERIAL SAFETY DATA SHEET (As per EC Regulation 1272/2008) Page 1 of 8 Date of Issue : 16/09/2018 Version : 5 Arabian Zinc Oxide Factory hazardous substance, solid, n. 3 Possibility of hazardous reactions No data available 10. 3. A zinc and copper alloy is used to make pennies in the United States. And those free radicals can damage your cells and DNA, most Tin zinc oxide (SnZnO3) | O3SnZn | CID 82851 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. P391: Collect spillage. This cargo, also named waelz oxide, is an odourless fine powder that aggregates into lumps. Possibility of hazardous reactions: Zinc oxide and magnesium metal fillings or powder can react violently when heated. 2015 Page 6 of 7 MSDS FOR ZINC OXIDE: KADOX 911, 911P, 911H, 915, 920, 920P, 920H, 920G, 930, 930H, 930G ZC-X006 SECTION I - GENERAL INFORMATION the hazards connected with the use of the material, or the results to be obtained from the use thereof. Common Name: ZINC BORATE CAS Number: 1332-07-6 DOT Number: NA 9155 ----- HAZARD SUMMARY * Zinc Borate can affect you when breathed in. Publication types Dentsply Sirona Pty Ltd Chemwatch Hazard Alert Code: 1 Dentsply IRM Powder Chemwatch: 8108-20 Version No: 5. Reproductive Hazard f Zinc appears to affect the male reproductive system (including sperm count). 2021. (Zinc Oxide) 9 III Hazard identification number 90 . Zinc oxide Revision Date 24-Dec-2021 Endocrine Disruptor Information No information available Other Adverse Effects The toxicological properties have not been fully investigated. These two chemicals also share in common the ability to form wurtzite (hexagonal) crystal structures. 98 at 5mM of Zinc SECTION 1: Identification of the substance/mixture and of the company/undertaking 1. In recent years zinc oxide has promoted itself as a interesting metal oxide material because of its The use of zinc in standard glazes is limited by its price, its hostility to the development of certain colors and its tendency to make glazes more leachable in acids (although zinc itself is not considered a hazardous substance). Zinc oxide is an amphoteric oxide. Nanocrystalline zinc oxide for the decontamination of sarin. 2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, Synthesis of substances No hazard pictogram, no signal word, no hazard statement(s), no precautionary statement(s) required Recently, the CIR SSC proposed that Zinc Oxide should be added to the report. 3 Advice for firefighters In case of fire and/or explosion do not breathe fumes. It is found in air, soil, and water, and is present in all foods. UN3077: ENVIRONMENTALLY HAZARDOUS SUBSTANCE SOLID N. S. Such toxicity levels have been seen to occur at ingestion of greater than 50 mg of zinc. Zinc powder stabilized: Combustible solid, UN number: 3077, Hazard class: 9, Packing group: III; GHS: Warning, H400, H410. 2 Materials to avoid Strong oxidizing agents. Fight fire with normal precautions from a reas- Zinc melts at about 790 °F and boils to vapor at about 1650 °F. However, they were reported to have toxicological hazards as well. Zinc oxide is a filter consisting of charcoal impregnated with zinc oxide and iron oxide removes significant amounts of HCN and H2S from tobacco smoke without affecting its flavor. Zinc oxide is commonly associated with metal fume fever. Volume 165, Issues 1–3, 15 June 2009, Pages 928-932. It is effective to soothe skin affected by rashes, allergies or irritation. ) are limited. First-aid measures Description of first aid measures General information Get medical attention immediately. Food and Drug Administration classified ZnO as a “generally regarded as safe Zinc is one of the most common elements in the earth's crust. If in doubt, contact a POISON CENTRE (0800 764 766) or a doctor. In this review, we focus on zinc oxide nanoparticles destined for use in modern sunscreens, and discuss the potential for human exposure and the health hazard at each stage of their manufacture and use. Journal of Hazardous Materials. * * O testing expiration is 12 mos from date of manuf acturing (DOM) for >= 8. USA: TSCA (Toxic Substances Control Act) inventory: Listed SARA Section 311/312 (40 CFR 370) Hazard Categories: Immediate Hazard: Zinc Oxide AZ066 Zinc Oxide RGT-66T Zinc Oxide RGT-66USP Zinc Oxide RGT-77HT Zinc Oxide RGT-H Zinc Oxide RGT-M Zinc Oxide FP-MA Zinc Oxide USP-2 Zinc Oxide XF-H Zinc Oxide XF-MA Zinc Oxide XFT-H Zinc Oxide XFT-MA Inhalation Hazards of Zinc Oxide Particles in Industrial Settings. Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-10507 ZINC OXIDE: ICSC: 0208 (April 2017) Zinc white Zinc monoxide C. 1 Classification of the substance or mixture Classification acc. Possibility of hazardous reactions: Under normal conditions of storage and use, hazardous reactions will not occur. 4. agents and as gene carriers. , ACS article number: T114 Version: 5. 5 and 5 mg/m 3 on separate days. 25 sat conc (20°C) Melting Point/Range 394 °C / 741. 6 mM) were applied to check the impact on plant growth attributes, National Guide for Classifying Hazardous Chemicals under the Model WHS Regulations Hazard Classification NOT hazardous according to the criteria of Safe Work Australia under Model WHS Regulations Chemical Entity Formula CAS Number Proportion Zinc oxide ZnO 1314-13-2 <=100 % May contain: Magnesium oxide MgO 1309-48-4 0 - 4 % Ingredients 3. Boron zinc oxide (B6Zn2O11), hydrate chemical information summary. Pulpdent Corporation Revision Date: February 10, 2021 Safety Data Sheet Trade Name: ZINC OXIDE POWDER 4 / 5 9. You can check the MSDS for the zinc oxide you buy to see what the chemical analysis is -- likely any lead is below acceptable levels established by the government. Foliar spraying with ZnO NPs improved Cd tolerance by increasing photosynthesis efficiency and antioxidative capacity, while it reduced Cd accumulation by 40. Recent studies have shown that zinc oxide nanoparticles can be toxic to humans ZINC OXIDE: ICSC: 0208 (April 2017) Zinc white Zinc monoxide C. The likelihood of producing the zinc vapor in significant quantities goes up with reduced thickness of the workpiece. Other adverse effects Very toxic to aquatic life with long lasting effects. Carcinogenicity: No known significant effects or critical hazards. Zinc oxide is a versatile compound with a wide range of applications across various industries. Cadmium stress is a major threat to plant growth and survival worldwide. In this experiment, two cadmium levels (0, 0. Zinc oxide is a toxic hazard -- it can have lead impurities. 3 Hazardous decomposition products Zinc/zinc oxide under fire condition. Its colour could be light brown or greyish yellow/greyish green. Zinc oxide is a nutrient supplement. We highlight where there is a need for further research. 10. : Volts: 1. I. In industrial settings where zinc oxide is manufactured or processed, workers are often exposed to fine zinc oxide particles Occupational exposure to freshly formed zinc oxide (ZnO) particles (less than 1. , Japan, Republic of Korea (ROK), Singapore and where zinc oxide is Slow degrade to zinc carbonate (not hazardous). Chlorinated rubber and zinc oxide react violently or explosively at about 216 ºC (in the presence or absence of hydrocarbon or halocarbon solvents). 5 Incompatible materials Strong oxidizing agents, Acids and bases Zinc oxide Germ cell mutagenicity Test Type: Ames test (zinc powder, zinc dust stabilized) zinc oxide 60-100% CAS number: 1314-13-2 M factor (Acute) = 1 M factor (Chronic) = 1 Classification Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 The full text for all hazard statements is displayed in Section 16. ALSO CALLED [185461-95-4] Zinc oxide (primary CASRN is 1314-13-2), [56592-00-8] Zinc oxide (primary CASRN is 131 View all synonyms (122) Hazards GreenScreen® for Safer Chemicals is a method for chemical hazard assessment designed to identify chemicals of high concern and safer alternatives. SECTION 6. In this study, the biochemical compositions of urine and kidney from the rats treated with ZnO NPs (100, 300 and 1000 mg/kg, respectively) were investigated using (1)H nuclear magnetic resonance (NMR) technique with the pattern "A standard is recommended for occupational exposure to zinc-oxide (1314132), including information on environmental standards, medical surveillance, labeling, personal protective equipment, informing employees of hazards, work practices, sanitation, monitoring and recordkeeping requirements. When I was a young surfer in California, zinc oxide sunscreen sticks were all the rage. Pigment White 4 Index No 030-013-00-7 CAS No 1314-13-2 Special hazards arising from the substance or mixture Do not allow run-off from fire-fighting to enter drains or water courses. At Identification of the substance Zinc oxide ≥99 %, Ph. In order to support the developing nanotechnology sector, comprehensive studies must be conducted to assess the toxicity of nanomaterials (NMs) using some time after exposure to Zinc and can last for months or years: Cancer Hazard f According to the information presently available to the New Jersey Department of Health, Zinc has not been tested for its ability to cause cancer in animals. Zinc oxide,8791E-3,17/04/2020 1/7 Date of issue: 23/03/2016 Date of revision: 17/04/2020 Safety Data Sheet 1. SAFETY data SHEET Conforms with OSHA Hazard Communication Standard (CFR 29 ) HazCom 2012 Product: zinc oxide (REF 310-16200, 310-16250, 310-16300) Revision Date: 11/09/2015 Page 1 of 12 zinc oxide (REF 310-16200, 310-16250, 310-16300) SDS SECTION 1 - IDENTIFICATION Product Identifier Product Name: zinc Product Description: Zinc oxide Cat No. Zinc Oxide. This generates fire and explosion All substances and mixtures must be checked for “environmentally hazardous (aquatic environment)” characteristics, even if already assigned to one or more of the classes 1 – 8 1. 0%, J-005999, ZINC OXIDE, SAJ FIRST GRADE, >=99. The pot experiment was conducted with Cd soil (19. 1 Product identifiers Product name : Zinc Oxide CAS-No. H410 - Very toxic to aquatic life with long lasting effects. Zinc oxide fumes formed during combustion may cause metal fume fever (see ICSC 0208). Health Hazards when Welding Galvanized Steel. Reactive or incompatible with the following materials: oxidizing materials. Zinc oxide is a constituent of cigarette filters for removal of selected components from tobacco smoke. Zinc has many commercial uses as coatings to prevent rust, in dry cell batteries, and mixed with other metals to make alloys like brass, and bronze. 58 / Monday, March 26, 2012 / Rules And Regulations and according to Canada’s Hazardous Products Regulation, February 11, 2015. Secondary constituents are lead oxides. 2 Relevant identified uses of the substance or mixture and uses advised against Applications of Zinc Oxide. Taking into account the lowest chronic ecotoxicity value Zinc-oxide nanoparticles (ZnO-NPs) have a diameter of less than 100 nanometers, high catalytic activity, The hazardous effects of Cd stress can be lessened with the efficacy of ZnO-NPs. The fumes and dust irritate the skin, eyes, lungs, mucous membranes and, if large quantities are inhaled in In this review, we focus on zinc oxide nanoparticles destined for use in modern sunscreens, and discuss the potential for human exposure and the health hazard at each stage of their manufacture and use. 20. Signal word: Warning. Nanotechnology is an emerging field that involves the synthesis of nanoscale particles having size of one dimension less than 100 nm (Baig et al. 2 en Replaces version of: 2024-09-18 Version: (5) date of compilation: 2016-09-13 SECTION 2: Hazards identification 2. GHS product identifier Other means of identification Product type Section 1. P. Continuous education and reinforcement of safety protocols help promote a culture of safety in the workplace and empower workers to protect themselves from potential health risks. At the same time, many published research studies showed the toxic effects of zinc oxide nanoparticles on some specific organs and cell lines. Prolonged inhalation of the dust may result in metal fume fever with symptoms of chills, fever, muscular pain, nausea and RonaCare® Zinc Oxide is a white or yellowish-white fine odorless powder. Zinc Oxide Zinc Oxide (ZnO) 99-100% 1314-13-2 215-222-5 030-013-00-7 3. 2 °F Choose lotion-based options that contain titanium dioxide or zinc oxide Skin cancer is the most common type of cancer in the United States , with 1 in 5 Americans likely to develop skin cancer The Hidden Dangers of Zinc Oxide Sunscreen. 06 December 2022 Zinc Metal Page 2 of 6 Zinc oxide and titanium dioxide are known photocatalysts, meaning that the substances can form free radicals as soon as they come into contact with sunlight. : Z/1350/60, Z/1350/70, Z/1350/53 Synonyms Chinese white; Zinc white; C. Two men exposed to about 600 mg/m 3 for 10. Zinc oxide. Ph Eur - Find MSDS or SDS, a COA, data sheets and more information. One of the great promises that nanoparticles of metal oxides hold in chemical applications is their remarkable ability to chemically absorb a wide variety of molecules, especially organic molecules that are concern as environmental hazards. When it hit the market, zinc oxide sunscreen was praised for its novel ability to block ZnO can also be obtained by incinerating zinc hydroxide, zinc nitrate, or zinc carbonate according to the following reaction: Zn (OH)2 (solid) → ZnO(solid) + H2O(liquid) Zinc oxide is primarily a UV-protective filter. MCCALL CSIRO Future Manufacturing Flagship, North Ryde, NSW, Australia SAFETY DATA SHEET - Integra Miltex. This flu-like illness presents symptoms such as a metallic taste in the mouth, headaches, fever, and chills. Precautionary Statement(s) P273: Avoid release to the environment. 2 mg kg-1) and foliar ZnO NPs (100 mg L-1) on alfalfa. 1 Conditions to avoid No data available 10. The results Some of the chemicals that lead to metal fume fever include zinc oxide, magnesium oxide, and aluminum oxide, among others, which are byproducts of fumes that result from the heating of metals. 4. Further considerations on the classification based on recent information. Pure zinc is a bluish-white shiny metal. 2 Special hazards arising from the substance: Hazards during fire – fighting: Phosphorus oxides and zinc oxide may be formed. 215-222-5 SECTION 2: HAZARDS IDENTIFICATION 2. Ingestion: No known significant effects or critical hazards. Here is how you know Zinc oxide CAS 1314-13-2 for analysis EMSURE® ACS,Reag. Zinc Oxide Diaper Rash: Clean the diaper area, make sure it’s wiped clean Hazard Statements H302 - Harmful if swallowed H314 - Causes severe skin burns and eye damage Zinc. Reproductive toxicity - category 1B . Zinc compounds that may be found at hazardous waste sites are zinc chloride, zinc oxide, zinc sulfate, and zinc sulfide. 5. Zinc Oxide Safety Data Sheet According to U. Inhalation: Exposure to airborne concentrations above statutory or recommended exposure limits may cause irritation of the nose, throat and lungs. Keywords:: Nanotoxicology; nanoparticle; FT-0640838, ZINC OXIDE NANODISPERSION TYPE C-CATIONIC (70NM), ZINC OXIDE, NANOPOWDER, <100 NM PARTICLE SIZE, D01170, FT-0645092, FT-0631786, ZINC OXIDE, JIS SPECIAL GRADE, >=99. The CLP Regulation makes sure that the hazards presented by chemicals are The U. The free zinc ion in solution is highly toxic to bacteria, plants, invertebrates, and even vertebrate fish. ” Tanguay said she was surprised that all five small-molecule mixtures were generally photostable but not surprised that adding zinc oxide particles led to toxicity upon UV irradiation. If the environmental hazard is the only hazard of a substance or mixture, the UN-numbers UN 3077 or UN 3082 are assigned. ZINC OXIDE AR Safety Data Sheet according to Regulation (EC) No. Hazardous Decomposition Products: High temperature operations such as oxy-acetylene cutting, electric arc welding or overheating of dried residues will generate zinc oxide fume which, on inhalation in sufficient quantity, can produce Acknowledging these dangers is vital for welders and individuals accountable for maintaining secure and healthy workspaces. Zinc compounds are widely used in industry. However, the bonds between zinc and oxygen therein bear considerable covalent character; covalent bonding was the rationale for excluding Zinc Sulfide from the report. A comprehensive understanding of its toxicity influenced by main factors driven by climate change is indispensable. ,Ltd. o. J:\Msds MSWord\OXIDE\ZCX006. (ZINC OXIDE) Transport Hazard Class(es) Hazard Identification Number: 90 Sea (IMO): DG, MP IATA Label: Miscellaneous Packing Group III III III Environmenta l Hazards Yes Yes, Dangerous to the Environment Yes Special Precautions Zinc oxide can be identified and quantified on three or more different angles of diffraction. The inevitable seepage into environmental matrices and the photoactive nature of ZnO NPs warrants hazard profiling under environmentally related conditions. Prolonged inhalation of the dust may result in metal fume fever with symptoms of chills, fever, muscular pain, nausea and These studies were undertaken in order to propose and test new methods for the assessment of the acute hazard of ZnO nanoparticles (NPs) to the sediment dwelling oligochaete worm Lumbriculus variegatus. The initial threshold screening level for zinc oxide [CAS # 1314-13-2] is 20 μg/m3 based on an 8-hour averaging time. Section 15: Other Regulatory Information. IMO / IMDG Classification In addition to zinc sulfate, other zinc compounds like zinc oxide and zinc gluconate also have a similar impact on the gastrointestinal system [45–47]. What Is Zinc Oxide Sunscreen? ZINC OXIDE This SDS Compliant for use in P. , USP Article number 5297 CAS number 1314-13-2 5. Toxic Mechanisms of Zinc Oxide Nanoparticles Zinc oxide nanoparticles are among the most important and multifunctional compounds.
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